Crossed Aldol Condensation Reactions between Various Aldehydes and Acetone Using Solid Base Catalysts
نویسندگان
چکیده
منابع مشابه
Aldol Condensation of Aldehydes and Ketones over Solid Base Catalysts
Introduction Industrially condensation reactions are of great importance in the production of a number of key compounds. These include 2-ethyl hexanol, methyl isobutyl ketone (MIBK) and Guerbet alcohols. Over 1.5 million tonnes of these chemicals are produced worldwide every year using homogeneous bases such as NaOH and Ca(OH)2. It has been estimated for these compounds that 30% of the selling ...
متن کاملMelamine trisulfonic acid as an efficient and reusable catalyst for the crossed-Aldol condensation of ketones and aldehydes under solvent-free conditions
Various types of aldehydes undergo crossed-Aldol condensation with ketones in the presence of melamine trisulfonic acid (MTSA) under solvent-free conditions. The reported method is mild, efficient and has the advantages such as using heterogeneous catalysis, short reaction times, high yields of the products and the recyclability of the catalyst.
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The Schiff base reaction and aldol condensation that occur during sample preparation can lead to the reduction of aldehyde content in the analysis of traditional Korean rice wine, makgeolli. The contents of aldehydes were decreased, whereas those of hydroxy carbonyl compounds were increased by increasing the pH. In the presence of added amino acids, the levels of aldehydes in makgeolli were red...
متن کاملMelamine trisulfonic acid as an efficient and reusable catalyst for the crossed-Aldol condensation of ketones and aldehydes under solvent-free conditions
Various types of aldehydes undergo crossed-Aldol condensation with ketones in the presence of melamine trisulfonic acid (MTSA) under solvent-free conditions. The reported method is mild, efficient and has the advantages such as using heterogeneous catalysis, short reaction times, high yields of the products and the recyclability of the catalyst.
متن کاملNanoplatelet-based reconstructed hydrotalcites: towards more efficient solid base catalysts in aldol condensations.
Rehydration of Mg-Al hydrotalcite in the liquid phase using ultrasounds or a high stirring speed leads to nanoplatelets with surface areas of 400 m(2) g(-1), displaying catalytic activities in aldol condensations up to 8 times higher than the best catalytic system reported in the literature.
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ژورنال
عنوان ژورنال: Journal of Japan Oil Chemists' Society
سال: 1994
ISSN: 1884-2003
DOI: 10.5650/jos1956.43.644